Poly[bis[μ2-2-(1H-1,2,4-triazol-1-yl)acetato]zinc(II)]
نویسندگان
چکیده
In the title compound, [Zn(C(4)H(4)N(3)O(2))(2)](n), the Zn(II) atom is coordinated by two O atoms [Zn-O = 1.969 (2) and 1.997 (2) Å] and two N atoms [Zn-N = 2.046 (2) and 2.001 (2) Å] in a distorted tetra-hedral geometry. Non-classical inter-molecular C-H⋯O hydrogen bonds link the complex into a three-dimensional supra-molecular framework.
منابع مشابه
A two-dimensional Zn coordination polymer with a three-dimensional supramolecular architecture
The title compound, poly[bis-{μ2-4,4'-bis-[(1,2,4-triazol-1-yl)meth-yl]biphenyl-κ2N4:N4'}bis-(nitrato-κO)zinc(II)], [Zn(NO3)2(C18H16N6)2] n , is a two-dimensional zinc coordination polymer constructed from 4,4'-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]-1,1'-biphenyl units. It was synthesized and characterized by elemental analysis and single-crystal X-ray diffraction. The ZnII cation is located on a...
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In the title complex, [Zn(C(14)H(9)N(5))(2)](ClO(4))(2), 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline functions as a tridentate ligand and the Zn(II) ion assumes a distorted octa-hedral ZnN(6) coordination geometry. There is a weak π-π stacking inter-action between symmetry-related triazolyl rings with a centroid-centroid distance of 3.802 (4) Å and a perpendicular distance of 3.413 Å between ...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009